Critical Survey of Stability Constants and Related Thermodynamic Data of Fluoride Complexes in Aqueous Solution

I. Introductory Comments on the Survey

A. Introduction

B. Techniques for measuring fluoride stability constants

1. The general characteristics of fluoride as a ligand

2. The "ferri" method

3. The fluoride ion-selective electrode method

4. Comparison of the two methods

5. Comments on the potentiometric determination of fluoride stability constants

C. Techniques for measuring enthalpies of fluoride complexation

1. Temperature dependence of stability constants

2. Direct calorimetry

D. Scope of the survey

1. Literature

2. Selection criteria

E. Presentation of data and explanation of the tables

1. Part A —Stability constant data

2. Part B — Enthalpy and entropy data

3. Part C — Summary of "best" values

F. References

II. The Data Tables

A. Stability constant data

B. Enthalpy and entropy data

C. Summary of "best" values

D. References