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Handbook of Crystal Growth

Bulk Crystal Growth

  • 2nd Edition, Volume 2A-2B - November 4, 2014
  • Latest edition
  • Editor: Peter Rudolph
  • Language: English

Vol 2A: Basic TechnologiesHandbook of Crystal Growth, Second Edition Volume IIA (Basic Technologies) presents basic growth technologies and modern crystal cutting methods. Parti… Read more

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Description

Vol 2A: Basic Technologies

Handbook of Crystal Growth, Second Edition Volume IIA (Basic Technologies) presents basic growth technologies and modern crystal cutting methods. Particularly, the methodical fundamentals and development of technology in the field of bulk crystallization on both industrial and research scales are explored. After an introductory chapter on the formation of minerals, ruling historically the basic crystal formation parameters, advanced basic technologies from melt, solution, and vapour being applied for research and production of the today most important materials, like silicon, semiconductor compounds and oxides are presented in detail. The interdisciplinary and general importance of crystal growth for human live are illustrated.

Vol 2B: Growth Mechanisms and Dynamics

Handbook of Crystal Growth, Second Edition Volume IIB (Growth Mechanisms and Dynamics) deals with characteristic mechanisms and dynamics accompanying each bulk crystal growth method discussed in Volume IIA. Before the atoms or molecules pass over from a position in the fluid medium (gas, melt or solution) to their place in the crystalline face they must be transported in the fluid over macroscopic distances by diffusion, buoyancy-driven convection, surface-tension-driven convection, and forced convection (rotation, acceleration, vibration, magnetic mixing). Further, the heat of fusion and the part carried by the species on their way to the crystal by conductive and convective transport must be dissipated in the solid phase by well-organized thermal conduction and radiation to maintain a stable propagating interface. Additionally, segregation and capillary phenomena play a decisional role for chemical composition and crystal shaping, respectively. Today, the increase of high-quality crystal yield, its size enlargement and reproducibility are imperative conditions to match the strong economy.

Key features

Volume 2A

  • Presents the status and future of Czochralski and float zone growth of dislocation-free silicon
  • Examines directional solidification of silicon ingots for photovoltaics, vertical gradient freeze of GaAs, CdTe for HF electronics and IR imaging as well as antiferromagnetic compounds and super alloys for turbine blades
  • Focuses on growth of dielectric and conducting oxide crystals for lasers and non-linear optics
  • Topics on hydrothermal, flux and vapour phase growth of III-nitrides, silicon carbide and diamond are explored

Volume 2B

  • Explores capillarity control of the crystal shape at the growth from the melt
  • Highlights modeling of heat and mass transport dynamics
  • Discusses control of convective melt processes by magnetic fields and vibration measures
  • Includes imperative information on the segregation phenomenon and validation of compositional homogeneity
  • Examines crystal defect generation mechanisms and their controllability
  • Illustrates proper automation modes for ensuring constant crystal growth process
  • Exhibits fundamentals of solution growth, gel growth of protein crystals, growth of superconductor materials and mass crystallization for food and pharmaceutical industries

Readership

Scientists and engineers from diverse (academic/industrial) backgrounds including crystal growers, physicists, chemists, engineers, bioengineers, solid state scientists, materials scientists, earth scientists, etc.

Table of contents

General Preface
Preface to Volume II
List of Contributors
Part A. Basic Techniques

1. Crystal Growth in Geology: Patterns on the Rocks

1.1. Introduction

1.2. Geological Scenarios for Crystal Growth

1.3. Deciphering Geological Information from Crystal Morphology

1.4. Decoding Polycrystalline Textures from Nucleation and Growth

1.5. The Case of Giant Crystals

1.6. Decoding Disequilibrium Mineral Patterns

1.7. Early Earth Mineral Growth, Primitive Life Detection, and Origin of Life

1.8. From Deep Earth to Outer Space

2. Czochralski Growth of Silicon Crystals

2.1. Introduction

2.2. Description of the Czochralski Process

2.3. Global Heat Transfer and Convective Flow

2.4. Transport and Incorporation of Dopants and Impurities

2.5. Oxygen in Silicon

2.6. Intrinsic Point Defects and Their Aggregates

2.7. Economic Aspects of Cz Growth

3. Liquid Encapsulation and Related Technologies for the Czochralski Growth of Semiconductor Compounds

3.1. Introduction

3.2. Pressure-Balancing Czochralski Growth

3.3. Growth Constraints to Crystal Quality in LEC and Related Technologies

3.4. Summary

4. Czochralski Growth of Oxides and Fluorides

4.1. Introduction

4.2. Sapphire Single Crystals

4.3. Calcium Fluoride Crystals

4.4. Large Fluoride Crystals

4.5. Scintillator Crystals

4.6. Summary and Outlook

5. Czochralski and Flux Growth of Crystals for Lasers and Nonlinear Optics

5.1. Laser Crystals Grown by the Czochralski Method

5.2. Nonlinear Optical Borate Crystals Grown by the Flux Method

5.3. Conclusion

6. Growth Measures to Achieve Bulk Single Crystals of Transparent Semiconducting and Conducting Oxides

6.1. Introduction

6.2. Basics of TSO Thermodynamics

6.3. Growth Techniques

6.4. Basic Electrical and Optical Properties of Bulk TSO Crystals

6.5. Summary

7. Floating Zone Growth of Silicon
Preface

7.1. Basics of the Floating Zone Silicon Crystal Growth

7.2. Automation of the Floating Zone Process Using Model-Based Control

7.3. Mathematical Modeling of the Floating Zone Silicon Growth

8. Floating Zone Growth of Oxides and Metallic Alloys

8.1. Optical Floating Zone—Complementary Crystal Growth Technique for New Classes of Oxide Materials

8.2. Floating-Zone Single Crystal Growth of Intermetallic Compounds Using a Two-phase RF Inductor

9. Vertical Bridgman Growth of Binary Compound Semiconductors

9.1. Introduction

9.2. Equipment (Design and Engineering Issues)

9.3. Growth of Binary Compound Semiconductors

9.4. Conclusions

10. Multicrystalline Silicon Crystal Growth for Photovoltaic Applications

10.1. Introduction

10.2. Ingot Growth Methods

10.3. Hot-zone Design

10.4. Nucleation and Grain Control

10.5. Conclusions

11. The Unidirectional Crystallization of Metals and Alloys (Turbine Blades)

11.1. Introduction

11.2. DS Castings Manufacturing

11.3. Nickel-based Superalloys and Heat Treatment Process

11.4. Methodology for Manufacture of Ceramic Shell Molds for Directional Solidification Casting

11.5. Investigation Methods for Directional Solidification Castings

11.6. Numerical Modeling of Thermal and Solidification Processes for Directional Solidification Castings

11.7. Summary

12. Crystal Growth by Traveling Heater Method

12.1. Introduction

12.2. Technology

12.3. Versatile THM

12.4. Materials Grown by THM

12.5. Segregation, Purification

12.6. Mass and Heat Transport, Simulation and Modeling

12.7. Single Crystal Growth by THM

12.8. Conclusions

13. Growth of Bulk Nitrides from a Na Flux

13.1. Introduction

13.2. Growth Conditions and Mechanism of the Na Flux Method

13.3. Nucleation Control

13.4. LPE Growth of GaN by the Na Flux Method

13.5. Point Seed and Coalescence Growth Technique

13.6. Summary

14. Hydrothermal Growth of Crystals—Design and Processing

14.1. Introduction

14.2. History of Hydrothermal Growth of Crystals and Current Trends in Hydrothermal Research

14.3. Intelligent Engineering of the Hydrothermal Processes

14.4. Apparatus

14.5. Hydrothermal Processing of Some Selected Crystals

14.6. Hydrothermal Growth of Fine to Nanocrystals

14.7. Conclusions

15. High-Pressure, High-Temperature Solution Growth and Ammonothermal Synthesis of Gallium Nitride Crystals

15.1. Introduction

15.2. High Nitrogen Pressure Solution Growth Method

15.3. Ammonothermal Growth of GaN

15.4. Overall Summary with an Outlook into the Future

16. Vapor Transport Growth of Wide Bandgap Materials

16.1. Introduction

16.2. High Temperature Sublimation Growth of Wide Bandgap Materials (SiC and AlN)

16.3. HVPE of Nitride Semiconductors (AlN, GaN, InN, and Ternary Alloys)

16.4. Conclusion

17. Crystal Growth of Diamond

17.1. Introduction

17.2. High Pressure Crystal Growth of Diamond

17.3. Growth of Diamond from Gas Phase

17.4. Applications

17.5. Conclusions

18. Wafer Processing

18.1. Introduction

18.2. Multi-wire Sawing Process

18.3. Determination of Wafer Properties

18.4. Basic Sawing Mechanisms

18.5. Alternative Slicing Technologies

18.6. Grinding, Lapping, and Polishing

18.7. Conclusions and Outlook
Part B. Growth Mechanisms and Dynamics

19. Capillarity and Shape Stability in Crystal Growth from the Melt

19.1. Introduction

19.2. Fundamentals of Capillarity for the Crystal Grower

19.3. Solutions of the Young–Laplace Equation

19.4. Shape Stability Analysis

19.5. Conclusions

20. Heat Transfer Analysis and Design for Bulk Crystal Growth: Perspectives on the Bridgman Method

20.1. Introduction

20.2. Historical Perspective: Experimental Practice

20.3. Heat Transfer Fundamentals

20.4. Heat Transfer in Melt Crystal Growth

20.5. Historical Perspective: Theoretical Developments

20.6. Research Vignette: Bridgman Growth of Cadmium Zinc Telluride

20.7. Final Remarks

21. Fluid Dynamics: Modeling and Analysis

21.1. Introduction

21.2. Diffusion

21.3. Natural and Forced Convections

21.4. External Fields

21.5. Flow Instability

21.6. Impurity Transfer

21.7. Summary

22. The Role of Marangoni Convection in Crystal Growth

22.1. Introduction

22.2. Surface Tension of Molten Materials

22.3. Marangoni Convection

22.4. Marangoni Convection in Crystal Growth

22.5. Concluding Remarks

23. Flow Control by Magnetic Fields during Crystal Growth from Melt

23.1. Introduction

23.2. Selected Fundamentals of Magnetohydrodynamics

23.3. Effects of Steady Magnetic Fields

23.4. Effects of Nonsteady Magnetic Fields

23.5. Combined Action of Various Types of Magnetic Fields and Electric Currents

23.6. Conclusions and Outlook

24. Oscillatory-Driven Fluid Flow Control during Crystal Growth from the Melt

24.1. Introduction

24.2. Constant-Speed Rotation in Melts

24.3. Accelerated Crucible Rotation Technique

24.4. Axial Vibration Control

24.5. Other Types of Oscillatory Techniques

24.6. Conclusions and Outlook

25. Segregation and Component Distribution

25.1. Introduction

25.2. Segregation Coefficients

25.3. Limit Theories: “Perfect Mixing” and “No-Mixing”

25.4. Convective Heat and Mass Transfer

25.5. Segregation Theories Based on Solute Layer Thickness

25.6. Segregation Model with Nusselt Numbers and Mixed Convection

25.7. Correlations for Nusselt Numbers

25.8. Directional Solidification: Segregation without Forced Convection

25.9. CZ Process: Segregation Controlled by Mixed Convection

25.10. Zone Melting

25.11. Lateral Segregation

25.12. Microsegregation

25.13. Summary

26. Thermal Stress and Dislocations in Bulk Crystal Growth

26.1. Overview

26.2. Thermal Stress in Bulk Single Crystals

26.3. Dislocations in Bulk Single Crystals

26.4. Summary

27. Defect Generation and Interaction during Crystal Growth

27.1. Introduction

27.2. Point Defects

27.3. Dislocations

27.4. Grain Boundaries

27.5. Foreign Phase Particles

27.6. Faceting and Twinning

27.7. Concluding Remarks

28. Automation of Crystal Growth from Melt

28.1. Introduction

28.2. Basics about Control Systems

28.3. Cz Process

28.4. Vertical Bridgman and Vertical Gradient Freeze Process

28.5. Detached Bridgman Process

28.6. Floating Zone Process

28.7. Kyropoulos Process

28.8. Conclusions

29. Fundamentals of Crystal Growth from Solutions

29.1. Introduction

29.2. Low-Temperature Solution Growth

29.3. High-Temperature Solution Growth

29.4. Summary and Outlook

30. Crystallization Mechanisms of High Critical Temperature Superconductors

30.1. Introduction

30.2. High Tc Oxide Superconductors

30.3. Requirement for Applications of HTSC Materials; Key Factors for Higher Jc

30.4. Phase Diagram of HTSC Material

30.5. Bulk Crystal Growth Methods from the Melt

30.6. Single Crystal Growth Methods from the Solution

30.7. Controlling Factors of Crystal Growth from the Melt and Solution

30.8. Crystal Growth Mechanism

30.9. Tetragonal to Orthorhombic Phase Transition (Twin Formation)

30.10. Conclusion

31. Crystallization in Gels

31.1. Introduction

31.2. Hydrogels, Organic Gels, and Aerogels

31.3. Crystal Growth in Gels of Small Molecules, Minerals, and Biological Macromolecules in Gels

31.4. General Remarks and Future of Crystal Growth in Gels

32. Fundamentals of Industrial Crystallization

32.1. Introduction

32.2. Product Quality

32.3. Crystallization

32.4. Crystal Nucleation

32.5. Crystal Growth

32.6. Crystallization Process Configuration

32.7. Ensuring Product Quality in the Future
Index

Review quotes

"...any library in the materials science or chemical engineering departments of universities should carry these volumes....I would recommend it to academics in the crystal growth field who want to have a complete reference work they can use to ensure their students are well grounded in the fundamentals and also to industrial crystal-growers who now and then need to understand why it is that what they do actually works."
— Advanced Materials

Product details

  • Edition: 2
  • Latest edition
  • Volume: 2A-2B
  • Published: November 4, 2014
  • Language: English

About the editor

PR

Peter Rudolph

Affiliations and expertise
Crystal Technology Consulting (CTC), Schönefeld, Germany

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