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Handbook of Nucleating Agents

Handbook of Nucleating Agents, Second Edition gives engineers and materials scientists the information they need to increase the production rate, modify structure and morpholog… Read more

Description

Handbook of Nucleating Agents, Second Edition gives engineers and materials scientists the information they need to increase the production rate, modify structure and morphology, improve mechanical performance, and reduce the haze of polymeric products through proper selection of nucleating agents (and/or the so-called clarifying agents). The book analyzes the existing literature paying special attention to recent developments, and is divided into 14 chapters, each of which concentrates on essential performances of nucleating agents. Chemical origin and related properties of nucleating agents are analyzed in general terms to highlight the differences in their properties and the book also provides the most essential theoretical knowledge required for proper selection and use of nucleating and clarifying agents. This includes polymer crystallization with and without nucleating agents, parameters of crystallization, essential influences on the nucleation processes, the measures of nucleation efficiency, the mechanisms of nucleation, and the effective methods of dispersion of nucleating agents. Later chapters concentrate on the application aspects in different formulations, outlining nineteen polymer processing methods which require use of nucleating agents, forty different polymers which are known to use nucleating agents, and sixteen applied examples of commercial products with nucleating agents. The final three chapters discuss the effects of nucleating agents on physical and mechanical properties of materials, the most essential analytical techniques, and health and safety in use of nucleating agents.

Key features

  • Enables engineers to use nucleating agents more effectively to increase production rate, modify structure and morphology, and reduce haze of polymer products
  • Provides a theoretical grounding required for proper selection and use of nucleating and clarifying agents
  • Offers an extensive review of current applications of nucleating agents in different formulations
  • Includes analysis of the chemical origin and related properties of nucleating agents to highlight differences in their properties

Readership

Researchers in materials science and engineering; professional material scientists and engineers
Secondary audience: Grad students and professors

Table of contents

1 Introduction

2 Chemical Origin of Nucleating Agents

2.1 Acids

2.2 Amides

2.3 Carbon nanotubes

2.4 Graphene derivatives

2.5 Hydrazides

2.6 Inorganic materials

2.6.1 Boron nitride

2.6.2 Calcium carbonate

2.6.3 Hydroxides and oxides

2.6.4 Silica

2.6.5 Talc

2.6.6 Others

2.7 Masterbatch

2.8 Phosphate salts

2.9 Polymeric

2.10 Proprietary nucleating agents

2.11 Renewable resouce

2.12 Salts of carboxylic acids

2.13 Sorbitol derivatives

2.14 Xylan esters

2.15 Other nucleating agents

3 Polymer Crystallization with and without Nucleating Agents

4 Parameters of Crystallization

5 What Influences Nucleation?

5.1 Concentration

5.2 Solubility of nucleating agent in polymer

5.3 Shear rate and time

5.4 Form of nucleating agent

5.5 Mixtures of nucleating agents

6 Nucleation Efficiency Measures

6.1 Nuclei density

6.2 Nucleation activity and constant

6.3 Nucleation efficiency

6.4 Activation energy

7 Mechanisms of Crystallization

8 Dispersion of Nucleating Agents

9 Nucleating Agents in Different Processing Methods

9.1 Blow molding

9.2 Blown film extrusion

9.3 Calendering

9.4 Compression molding

9.5 Dip coating

9.6 Extrusion

9.7 Foaming

9.8 Hot-melt coating

9.9 Injection molding

9.10 Micro-injection molding

9.11 Powder injection molding

9.12 Pultrusion

9.13 Reaction injection molding

9.14 Rotational molding

9.15 Sheet molding

9.16 Spinning

9.17 Thermoforming

9.18 Welding and machining

9.19 Wire coating

10 Application of Nucleating Agents in Specific Polymers

10.1 Poly(acrylonitrile-co-butadiene-co-styrene)

10.2 Cellulose acetate

10.3 Epoxy resin

10.4 Ethylene-propylene diene terpolymer

10.5 Ethylene-vinyl acetate copolymer

10.6 Fluorinated ethylene-propylene copolymer

10.7 Liquid crystalline polymer

10.8 Polyamide

10.9 Poly(acrylic acid)

10.10 Polyacrylonitrile

10.11 Polyaniline

10.12 Poly(butylene terephthalate)

10.13 Polycarbonate

10.14 Poly(-caprolactone)

10.15 Polychlorotrifluoroethylene

10.16 Polyethylene

10.17 Polyetheretherketone

10.18 Polyetherketoneketone

10.19 Poly(ethylene oxide)

10.20 Poly(ether sulfone)

10.21 Poly(ethylene terephthalate)

10.22 Polyethylene, silane-crosslinkable

10.23 Poly(glycolic acid)

10.24 Poly(3-hydroxybutyrate)

10.25 Poly(3-hydroxybutyrate-co-3-hydroxyvalerate)

10.26 Polyimide

10.27 Poly(lactic acid)

10.28 Polyoxymethylene

10.29 Polypropylene

10.30 Polyphthalamide

10.31 Poly(p-phenylene sulfide)

10.32 Polystyrene

10.33 Poly(trimethylene terephthalate)

10.34 Polyurethane

10.35 Poly(vinyl alcohol)

10.36 Poly(vinylidene fluoride)

10.37 Poly(vinylidene fluoride-co-hexafluoropropylene)

10.38 Poly(vinyl fluoride)

10.39 Poly(N-vinyl carbazole)

10.40 Unsaturated polyester

11 Nucleating Agents in Various Products

11.1 Adhesives

11.2 Aerospace

11.3 Appliances

11.4 Automotive materials

11.5 Bottles

11.6 Building construction

11.7 Cable & wire

11.8 Coatings & paints

11.9 Electronics and electrical

11.10 Fibers

11.11 Films

11.12 Medical applications

11.13 Pharmaceutical applications

11.14 Railway

11.15 Roofing

11.16 Window profiles

12 Effect of Nucleating Agents on Physical-mechanical Properties

12.1 Physical properties

12.1.1 Agglomeration

12.1.2 Aspect ratio

12.1.3 Crystalline structure

12.1.4 Hydrophilic/hydrophobic properties

12.1.5 Melting temperature

12.1.6 Moisture

12.1.7 Optical properties

12.1.8 Particle size

12.1.9 Refractive index

12.1.10 Shape memory

12.1.11 Solubility

12.1.12 Surface energy

12.1.13 Thermal conductivity

12.1.14 Transition temperature

12.1.15 Zeta potential

12.2 Mechanical properties

12.2.1 Flexural strength

12.2.2 Hardness

12.2.3 Impact strength

12.2.4 Residual stress

12.2.5 Scratch resistance

12.2.6 Shrinkage

12.2.7 Tear strength

12.2.8 Thermal deformation

12.2.9 Tensile strength

13 Important Analytical Methods Used in the Studies of Nucleating Agents

13.1 Crystallinity

13.2 Crystallization half-time

13.3 Differential scanning calorimetry

13.4 Fast scanning chip calorimetry

13.5 FTIR

13.6 Haze

13.7 Orientation degree

13.8 Polarized light microscopy

13.9 Quenching device

13.10 Small angle x-ray diffraction

13.11 Spherulite size

13.12 Thermogravimetric analysis

13.13 Vicat softening temperature

13.14 Wide angle x-ray diffraction

14 Health and Safety with Nucleating Agents

Product details

About the author

GW

George Wypych

George Wypych has a Ph.D. in chemical engineering. His professional expertise includes both university teaching (full professor) and research and development. He has published 18 books, 47 scientific papers, and he has obtained 16 patents. He specializes in polymer additives, polymer processing and formulation, material durability and the development of sealants and coatings.
Affiliations and expertise
ChemTec Publishing, Ontario, Canada

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