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Reactions of Importance in Synthesis

  • 1st Edition - January 1, 1994
  • Latest edition
  • Editor: James M. Coxon
  • Language: English

Advances in Detailed Reaction Mechanisms, Volume 3: Reactions of Importance in Synthesis presents the development, discoveries, and understanding of reactions of importance in… Read more

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Description

Advances in Detailed Reaction Mechanisms, Volume 3: Reactions of Importance in Synthesis presents the development, discoveries, and understanding of reactions of importance in synthesis. This book discusses the significance of the reaction to organic synthesis. Organized into seven chapters, this volume begins with an overview of the effects of Lewis acids, aldehyde structure, and addition order upon the diastereoselectivity. This text then discusses the origin of the differences in reactivity and energy between the substrate and transition state conformations. Other chapters consider the influence of organometallic chemistry on the development of methodology in organic synthesis. This book discusses as well the diversity of possible facially dissymmetric dienes and dienophiles, which can be persuaded to undergo a Diels–Alder reaction. The final chapter deals with the variety of methods for the construction of carbocyclic rings. This book is a valuable resource for industrial chemists, graduate students, postdoctoral fellows, and those teaching specialized topics to graduate students.

Table of contents


Contents

List of Contributors

Introduction to The Series: An Editor's Foreword

Preface

Stereochemistry and Mechanism of Allylic Tin-Aldehyde Condensation Reactions

Stereoeletronic Rules in Addition Reactions: "Cram's Rule" in Olefinic Systems


1,4-Addition Reactions of Organocuprates with α,β-Unsaturated Ketones

Diastereofacial Selectivity in the Diels-Alder Reaction

Template Effects of Distannoxanes

N-Alkylation of Nitrogen Azoles

Generation and Cyclization of Unsaturated Organolithiums

Index


Product details

  • Edition: 1
  • Latest edition
  • Published: January 1, 1994
  • Language: English