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Books in Chemistry

Chemistry topic areas include: physical and theoretical, computational, organic, organometallic and inorganic, pharmaceutical and medicinal, analytical and bioanalytical, nuclear, general, nanochemistry, geochemistry, materials and polymer, as well as environmental, green and sustainable chemistry.

  • The Theory of Kinetics

    • 1st Edition
    • Volume 2
    • R.G. Compton + 2 more
    • English
    The Theory of Kinetics covers the practice and theory of kinetics and the kinetics of inorganic and organic reactions in gaseous and condensed phases and at interfaces. This text is composed of five chapters and starts with a review of the kinetic characterization of complex reaction systems. The succeeding chapter describes the formal and radical kinetics, as well as the energy factor in chain reactions. These topics are followed by a survey of the theory of the kinetics of elementary gas phase reactions and the unimolecular reaction of activated chemical species. The discussion then shifts to the general properties, reactions, and the theory of elementary reactions in solution. The last chapter examines the theory of kinetics of solid-state reactions. This book is of great value to physical, inorganic, and organic chemists.
  • Computational Statistical Mechanics

    • 1st Edition
    • W.G. Hoover
    • English
    Computational Statistical Mechanics describes the use of fast computers to simulate the equilibrium and nonequilibrium properties of gases, liquids, and solids at, and away from equilibrium. The underlying theory is developed from basic principles and illustrated by applying it to the simplest possible examples.Thermodynam... based on the ideal gas thermometer, is related to Gibb's statistical mechanics through the use of Nosé-Hoover heat reservoirs. These reservoirs use integral feedback to control temperature. The same approach is carried through to the simulation and analysis of nonequilibrium mass, momentum, and energy flows. Such a unified approach makes possible consistent mechanical definitions of temperature, stress, and heat flux which lead to a microscopic demonstration of the Second Law of Thermodynamics directly from mechanics. The intimate connection linking Lyapunov-unstable microscopic motions to macroscopic dissipative flows through multifractal phase-space structures is illustrated with many examples from the recent literature.The book is well-suited for undergraduate courses in advanced thermodynamics, statistical mechanic and transport theory, and graduate courses in physics and chemistry.
  • Advances in Standards and Methodology in Spectrophotometry

    • 1st Edition
    • Volume 2
    • C. Burgess + 1 more
    • English
    These conference proceedings form a worthy contribution to the literature on spectrometry reviving the tradition begun at the U.S. National Bureau of Standards conferences in the 1970's of holding interdisciplinary conferences on advances in the standardisation and methodology of spectrometry. The papers and poster abstracts presented in this volume maintain the high professional standards of these earlier NBS conferences, providing a basis for further progress in this discipline.
  • Alkali Metal Orthophosphates

    • 1st Edition
    • Volume 31
    • J. Eysseltova + 1 more
    • English
    This volume presents and evaluates reported solubility data for the title compounds, complementing an earlier volume in the IUPAC Solubility Data Series dealing with alkali metal halides. Orthophosphates have been known and used for many years; principal applications include their use in fertilizers, as corrosion inhibitors and in piezoelectric components. Most published data relate to sodium and potassium orthophosphates; introductory chapters on these two systems are followed by chapters dealing with individual phosphates with various metal/phosphorus ratios, together with coverage of ternary and multicomponent systems. In compiling the data, all relevant articles published up to 1984 have been consulted. Critical evaluation of the data has made possible the definition of recommended solubility values.
  • The Chemical Physics of Solid Surfaces and Heterogeneous Catalysis

    • 1st Edition
    • D.A. King
    • English
    Surface Properties of Electronic Materials is the fifth volume of the series, The Chemical Physics of Solid Surfaces and Heterogeneous Catalysis. This volume indicates the present state of some basic properties of semiconductor surfaces. Chapter one summarizes the general problems in electronic materials and the areas affected by the surface science methods. The next two chapters illustrate the existing perception of the electronic and structural properties of elemental and compound semiconductor surfaces. This volume also deals with the properties of adsorption of semiconductors relating to both relevant gas phase species and metals. Chapters four to six of this volume explore compound semiconductors and elemental semiconductors. The remaining chapters of this volume explore the adsorption of metals on elemental semiconductors; aspects of growth kinetics and dynamics involved in molecular beam epitaxy; molecular beam epitaxy of silicon; insulators; and metastable phases. The last chapter covers the surface chemistry of dry etching processes.
  • Physico-Chemical Properties of Selected Anionic, Cationic and Nonionic Surfactants

    • 1st Edition
    • N.M. van Os + 2 more
    • English
    The number of physico-chemical investigations of surfactants in solution, whether aqueous or nonaqueous, has dramatically increased in recent years. However, literature reports on surfactants in solutions are scattered over a plethora of scientific journals and books which differ widely in scope and readership. Such data are often difficult to retrieve because there have been no systematic compilations, with the exception of those for CMCs and for micelle aggregation numbers. The present compilation meets that need by covering, as completely as possible, the physico-chemical properties of selected series of homologous surfactants. These surfactants are in most cases isomerically pure, are well-known, and have been used in numerous academic and industrial studies. The properties include aggregation number, cloud point, CMC, 13C-NMR, correlation length, counterion binding, density, enthalpy of micelle formation, entropy of micelle formation, Gibbs' free energy of micelle formation, head group area, 1H-NMR, hydration number, Krafft temperature, melting point, micelle radius, microscopic viscosity, miscibility curve, partial molar volume, phase inversion temperature, refractive index, self-diffusion coefficient, surface tension, and upper critical temperature. The book also contains two- and three-component phase diagrams of many nonionic surfactants.The solvent is water in most cases; however, some data refer to properties in D2O, electrolyte solutions, and nonaqueous solvents. The variables are temperature and concentration. Where possible, the method of measurement is given. Data on the purity of the compounds and the accuracy of the measurement methods are not included, as these can easily be found in the original sources, which mostly date from the period 1970-1991 and are given at the end of each chapter. The Index section contains a compound index, a property index, a symbol index and a cross index which facilitate easy access to the data.This valuable collection of data will be of great use to anyone involved in Colloid and Surface Science, academics as well as industrial workers, and will stimulate further work.
  • Dielectrics in Time-Dependent Fields

    • 2nd Edition
    • Bozzano G Luisa
    • English
    Theory of Electric Polarization, Volume II: Dielectrics in Time-Dependent Fields focuses on the processes, reactions, and principles involved in the application of dielectrics in time-dependent fields, as well as the Kerr effect, statistical mechanics, and polarization. The publication first examines the phenomenological theory of linear dielectrics in time-dependent fields; empirical description of dielectric relaxation; and the relationship between macroscopic and molecular dielectric relaxation behavior. Concerns cover the relationship between macroscopic and microscopic correlation functions; statistical mechanics of linear dissipative systems and the relationship between response functions and correlation functions; superpositions of distribution functions; and the use of complex dielectric constant in problems with time-dependent field sources. The book then ponders on the dipole correlation function, polarization in the infrared and optical frequency range, and the Kerr effect and related phenomena. Discussions focus on the Kerr effect in condensed systems, extensions of the Kerr effect, extrapolation of the refractive index to infinite wavelength, results obtained from computer simulations, rotational diffusion, and general aspects of molecular reorientation. The manuscript tackles the dielectric properties of molecular solids and liquid crystals and experimental determination of permanent dipole and quadrupole moments. The text is a valuable source of data for researchers interested in the application of dielectrics in time-dependent fields.
  • Solvation, Ionic and Complex Formation Reactions in Non-Aqeuous Solvents

    • 1st Edition
    • Volume 6
    • K. Burger
    • English
    Solvation, Ionic and Complex Formation Reactions in Non-Aqueous Solvents: Experimental Methods for their Investigation presents the available methods and their particular value in investigating solutions composed of non-aqueous solvents. This book is composed of 10 chapters and begins with a brief description of the complexity of the interactions possible n solutions. The subsequent chapters deal with a classification of the solvents and empirical solvent strength scales based on various experimental parameters, together with various correlations empirically describing the solvent effect. Other chapters present the methods for the purification of solvents and ways of checking their purity, as well as the individual results achieved during investigations of the solvent effect, particularly the general regularities recognized. The remaining chapters provide a review of the coordination chemistry of non-aqueous solutions. This book will prove useful to analytical and inorganic chemists.
  • Research in Chemical Kinetics

    • 1st Edition
    • Bozzano G Luisa
    • English
    This series of volumes aims to publish authoritative review articles on a wide range of exciting and contemporary topics in gas and condensed phase kinetics. Research in Chemical Kinetics complements the acclaimed series Comprehensive Chemical Kinetics, and is edited by the same team of professionals.The reviews contained in this volume are concise, topical accounts of specific research written by acknowledged experts. The authors summarize their latest work and place it in a general context. Particular strengths of the volume are the quality of the contributions and their topicality, and the rapid publication realized.
  • Molecular Design

    Chemical Structure Generation from the Properties of Pure Organic Compounds
    • 1st Edition
    • Volume 75
    • A.L. Horvath
    • English
    This book is a systematic presentation of the methods that have been developed for the interpretation of molecular modeling to the design of new chemicals. The main feature of the compilation is the co-ordination of the various scientific disciplines required for the generation of new compounds. The five chapters deal with such areas as structure and properties of organic compounds, relationships between structure and properties, and models for structure generation. The subject is covered in sufficient depth to provide readers with the necessary background to understand the modeling techniques. The book will be of value to chemists in industries involved in the manufacture of organic chemicals such as solvents refrigerants, blood substitutes, etc. It also serves as a reference work for researchers, academics, consultants, and students interested in molecular design.