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Pergamon

  • Comprehensive Organometallic Chemistry II, Volume 6

    Manganese Group
    • 1st Edition
    • C.P. Casey
    • English
    This volume provides an update on the chemistry of manganese, technetium and rhenium covered in Volume 4 of COMC. The literature surveyed is from 1982 to 1993. The explosive growth in organorhenium chemistry, the use of manganese hydrocarbon complexes in organic synthesis, and the development of the chemistry of high oxidation manganese and rhenium compounds are highlighted. The growth of organotechnetium chemistry which was virtually unknown at the time of COMC is covered in depth.
  • Comprehensive Organometallic Chemistry II, Volume 8

    Cobalt, Rhodium and Iridium
    • 1st Edition
    • J.D. Atwood
    • English
    This volume covers the advances of organometallic chemistry of cobalt, rhodium and iridium from 1982 to 1993 with over 3,000 references not previously included in COMC. It incorporates recent developments including carbon-hydrogen activation systems and C60 and C70 complexes that have been discovered since the original publication of COMC.
  • Comprehensive Organometallic Chemistry II, Volume 3

    Copper and Zinc Groups
    • 1st Edition
    • J.L. Wardell
    • English
  • Comprehensive Organometallic Chemistry II, Volume 2

    Silicon Group, Arsenic, Antimony and Bismuth
    • 1st Edition
    • A.G. Davies
    • English
    A common theme within this section (Si, Ge and Sn), is the use of bulky groups to stabilize species which are otherwise unknown. This includes the divalent species R2M, the trivalent radicals R3M0, and the multiply-bonded compounds R2M=MR2, R2M=CR2, etc. A significant difference from COMC is the much greater availability of single crystal x-ray diffraction and this is covered. Other important developments covered include, silicone polymers derived from carbofunctional silanes and the developments in polysilane high polymers. The Sn chapter covers the biggest development, the use of organotin compounds in organic synthesis, and this chapter provides the background information.
  • Comprehensive Organometallic Chemistry II, Volume 14

    Comprehensive Organometallic Chemistry II: A Review of the Literature 1982-1994: Cumulative Indexes
    • 1st Edition
    • Edward W. Abel
    • English
    Since the publication Comprehensive Organometallic Chemistry in 1982, studies on the chemistry of moleculeswith carbon-metal bonds have continued to expand rapidly. This is due to many factors, ranging from the sheer intellectual challenge and excitement provided by the continuing production of novel results, which demand new ideas, through to the successful application of organometallic species in organic syntheses, the generation of living catalysts for polymerization, and the synthesis of precursors for materials employed in the electronic and ceramic industries. These factors led to the publication of the updated Comprehensive Organometallic Chemistry II. The original work serves as a basis for new volumes, focusing on organometallic chemistry reported since 1982, with reference back to the original work when necessary. For ease of use the new volumes maintain the same general structure as employed previously but reflect the changes in substance and direction the field has undergone in the last ten years. This book will serve as a pivotal reference point for new work and will function to generate new ideas and perceptions for the continued advance of what will surely continue as a vibrant area of chemistry.
  • An End to Global Warming

    • 1st Edition
    • L.O. Williams
    • English
    The 6+ billion inhabitants of earth aspire to higher standards of living. This takes energy. If fossil fuels continue to be the key source of energy their waste product, carbon dioxide, will produce disagreeable changes in the climate. Depletion of fossil fuels will cause the cost of energy and fuel based chemicals to spiral. Climate change and high fuel prices will thwart these aspirations and will increase the probability of lethal international conflicts over energy supplies. We must stop using fossil fuels.Optimistically... we could switch from fossil fuels to renewable energy sources (solar, wind, etc.). Regrettably these sources are difficult to harvest and unreliable. They cannot, alone, serve as a base load energy supply for humanity. Fission nuclear power yields extremely hazardous waste for which no fully agreeable disposal method has been developed.Laurence Williams applied aerospace systems analysis techniques to seek a new energy system. An End to Global Warming presents his results. He shows why we must stop using fossil fuels and evaluates a host of alternatives to arrive at a robust energy system that will modernize world energy production and protect the environment. A by-product of this system will ameliorate problems associated with supplying potable water and in processing waste. The nations that develop the system described in An End to Global Warming will be gifted with huge financial reward and the pride in knowing that they have preserved the earth for all mankind.
  • Time Delay Systems 2001

    • 1st Edition
    • K. Gu + 2 more
    • English
    These Proceedings contain the papers presented at the 3rd IFAC International Workshop on Time Delay Systems, Santa Fe, New Mexico, USA, 8 - 10 December 2001. The first workshop in this series took place in Grenoble, France, 1998 and the second workshop was held in Ancona, Italy, 2000. This workshop's scope has expanded to include nonlinear systems. This workshop also contains various "new" applications of delay systems including those of communication networks and computing. The effects of delay are currently being felt in many research areas and this workshop was held in an attempt to bring together researchers from various technical fields in order to advance our understanding of delay phenomena in dynamical systems.
  • Periodic Control Systems 2001

    • 1st Edition
    • S. Bittanti + 1 more
    • English
    Periodic control has reached a notable degree of maturity thanks to developments over the last few decades. We have seen not only major theoretical achievements but also new significant applications. The IFAC workshop on Periodic Control Systems (PSYCO 2001), held at the Villa Erba Congress Centre in Cernobbio-Como (Italy), August 27-28 2001, aimed at presenting the full picture of the area by gathering experts in the field and all interested researchers, coming from universities, research institutions and industries. The program consisted of technical sessions, organized in two parallel streams and two plenary lectures, given by Jason L. Speyer (University of California at Los Angeles, USA) and Yutaka Yamamoto (Kyoto University, Japan). The technical sessions included 42 papers covering the following subjects:•Periodic Systems Analysis•Application... and Sampled-Data•Aerospa... Applications•Periodi... Systems Control•Numerical Methods•Multirate and Batch Processes•Repetitive and Nonlinear ControlA dozen of the papers were devoted to a number of applications, including aerospace, jet and diesel engines, gas turbines, nuclear reactors, power systems, satellites, environmental sciences and finance.
  • Organolithiums: Selectivity for Synthesis

    • 1st Edition
    • Volume 23
    • Jonathan Clayden
    • English
    This volume, number 23 in the "Tetrahedron Organic Chemistry" series, presents organolithium chemistry from the perspective of a synthetic organic chemist, drawing from the synthetic literature to present a unified overview of how organolithiums can be used to make molecules. The development of methods for the regioselective synthesis of organolithiums has replaced their image of indiscriminate high reactivity with one of controllable and subtle selectivity. Organolithium chemistry has a central role in the selective construction of C-C bonds in both simple and complex molecules, and for example has arguably overtaken aromatic electrophilic substitution as the most powerful method for regioselective functionalisation of aromatic rings. The twin themes of reactivity and selectivity run through the book, which reviews the ways by which organolithiums may be formed and the ways in which they react. Topics include advances in directed metallation, reductive lithiation and organolithium cyclisation reactions, along with a discussion of organolithium stereochemistry and the role played by ligands such as (-)-sparteine.
  • Organolithiums: Selectivity for Synthesis

    • 1st Edition
    • Volume 23
    • Jonathan Clayden
    • English
    This volume, number 23 in the "Tetrahedron Organic Chemistry" series, presents organolithium chemistry from the perspective of a synthetic organic chemist, drawing from the synthetic literature to present a unified overview of how organolithiums can be used to make molecules. The development of methods for the regioselective synthesis of organolithiums has replaced their image of indiscriminate high reactivity with one of controllable and subtle selectivity. Organolithium chemistry has a central role in the selective construction of C-C bonds in both simple and complex molecules, and for example has arguably overtaken aromatic electrophilic substitution as the most powerful method for regioselective functionalisation of aromatic rings. The twin themes of reactivity and selectivity run through the book, which reviews the ways by which organolithiums may be formed and the ways in which they react. Topics include advances in directed metallation, reductive lithiation and organolithium cyclisation reactions, along with a discussion of organolithium stereochemistry and the role played by ligands such as (-)-sparteine.